Please use this identifier to cite or link to this item: http://buratest.brunel.ac.uk/handle/2438/13165
Title: Study on utilization of carboxyl group decorated carbon nanotubes and carbonation reaction for improving strengths and microstructures of cement paste
Authors: Yan, X
Cui, H
Qin, Q
Tang, W
Zhou, X
Keywords: Carbon nanotube;Carbonation;Functional group;Calcium carbonate;Crystal morphology;Strength
Issue Date: 2016
Publisher: MPDI
Citation: Nanomaterials, 6 (8): (2016)
Abstract: Carbon nanotubes (CNTs) have excellent mechanical properties and can be used to reinforce cement-based materials. On the other hand, the reaction product of carbonation with hydroxides in hydrated cement paste can reduce the porosity of cement-based materials. In this study, a novel method to improve the strength of cement paste was developed through a synergy of carbon nanotubes decorated with carboxyl group and carbonation reactions. The experimental results showed that the carboxyl group (–COOH) of decorated carbon nanotubes and the surfactant can control the morphology of the calcium carbonate crystal of carbonation products in hydrated cement paste. The spindle-like calcium carbonate crystals showed great morphological differences from those observed in the conventional carbonation of cement paste. The spindle-like calcium carbonate crystals can serve as fiber-like reinforcements to reinforce the cement paste. By the synergy of the carbon nanotubes and carbonation reactions, the compressive and flexural strengths of cement paste were significantly improved and increased by 14% and 55%, respectively, when compared to those of plain cement paste.
URI: http://bura.brunel.ac.uk/handle/2438/13165
DOI: http://dx.doi.org/10.3390/nano6080153
ISSN: 2079-4991
Appears in Collections:Dept of Mechanical Aerospace and Civil Engineering Research Papers

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